That’s just it in a (nut)shell. Let’s say the curved side has a slightly higher probability of being “down” due to the center of gravity being off-center a little bit. Say curved side down is 51% chance … i.e. consistently throw it hundreds of times and consistently observe per 100 throws it lands 51 times curved side down, 49 times curved side up.
If you throw two of them at the same time, then the probability of getting both curved up or both curved down is 49% vs 51%. You could throw 5000 of these things together, and if they are identically made and have the 51%/49% “nature” then the probability of all these independent trials taken together is always 51/49, because they are independent events.
But if you throw one, and then throw it again, compound probability means the probability of curved side down twice is 51% x 51% = 26%. So multiple sequential throws are going to favor the curved side down, vs. flat side down, which is 49% x 49% = 24%.
I.e. it doesn’t pay to have lots of unfair shells. It pays to have one good one and use it a lot.