Jeff talks with his former colleagues at StackExchange.Interview and Podcast
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Some other Discourse related audio and video, if you are a glutton for punishment:
A very well received presentation at ForumCon, audio and video with slides side by side. Hard to explain, but I recommend this one, try the first 10 or 15 minutes and see if it grabs you:
Podcast with Ruby developers about Discourse. Not super technical, lots of background:
http://rubyrogues.com/106-rr-discourse-with-jeff-atwood/
Podcast with the changelog, open source developer blog, about Discourse. Also not particularly technical.